Synthesis and structure of aqua-2′,2‴-(2,6-pyridindiyldiethylidene)dioxamohydrazide-copper(II) hydrate

Andjelkovic K, Ivanovic-Burmazovic I, Niketic SR, Prelesnik B, Leovac V (1997)

Publication Type: Journal article, Original article

Publication year: 1997

Journal

Polyhedron Elsevier

Original Authors: Andjelković K., Ivanović I., Niketić S., Prelesnik B., Leovac V.

Publisher: Elsevier

Book Volume: 16

Pages Range: 4221-4228

Journal Issue: 24

URI: https://www.scopus.com/record/display.uri?eid=2-s2.0-0001380606&origin=inward

Abstract

In a template synthesis from copper(II) acetate, 2,6-diacetylpyridine, and semioxamazide (NHCO CONHNH), two new copper(II) complexes, [Cu(dapsox)(HO)] · H2O and [Cu(dapsox)(HO)]ClO, (where Hdapsox = 2′,2‴-(2,6-pyridindiyldiethylidene)dioxamohydrazide) were obtained and characterized. The structure of the former complex was determined by a single-crystal X-ray analysis. Cu is located in a square pyramidal environment. The polydentate ligand, dapsox, is coordinated in dianionic form, as an unsymmetrical quadridentate planar system forming one six-membered and two five-membered metal-chelate rings. The fifth coordination site is occupied by a water molecule. © 1997 Elsevier Science Ltd.

Authors with CRIS profile

Ivana Ivanovic-Burmazovic Lehrstuhl für Bioanorganische Chemie

How to cite

APA:

Andjelkovic, K., Ivanovic-Burmazovic, I., Niketic, S.R., Prelesnik, B., & Leovac, V. (1997). Synthesis and structure of aqua-2′,2‴-(2,6-pyridindiyldiethylidene)dioxamohydrazide-copper(II) hydrate. Polyhedron, 16(24), 4221-4228.

MLA:

Andjelkovic, K., et al. "Synthesis and structure of aqua-2′,2‴-(2,6-pyridindiyldiethylidene)dioxamohydrazide-copper(II) hydrate." Polyhedron 16.24 (1997): 4221-4228.

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