Reversible Activation and Transfer of White Phosphorus by Silyl-Stannylene

Sarkar D, Weetman C, Munz D, Inoue S (2020)

Publication Type: Journal article

Publication year: 2020

Journal

Angewandte Chemie International Edition Wiley

DOI: 10.1002/anie.202013423

Abstract

Use of a silyl supported stannylene (^MesTerSn(Si^tBu3) [^MesTer=2,6-(2,4,6-Me3C6H2)2C6H3] enables activation of white phosphorus under mild conditions, which is reversible under UV light. The reaction of a silylene chloride with the activated P4 complex results in facile P-atom transfer. The computational analysis rationalizes the electronic features and high reactivity of the heteroleptic silyl-substituted stannylene in contrast to the previously reported bis(aryl)stannylene.

Authors with CRIS profile

Dominik Munz Lehrstuhl für Anorganische und Allgemeine Chemie

Involved external institutions

Technische Universität München (TUM)

Germany (DE)

How to cite

APA:

Sarkar, D., Weetman, C., Munz, D., & Inoue, S. (2020). Reversible Activation and Transfer of White Phosphorus by Silyl-Stannylene. Angewandte Chemie International Edition. https://doi.org/10.1002/anie.202013423

MLA:

Sarkar, Debotra, et al. "Reversible Activation and Transfer of White Phosphorus by Silyl-Stannylene." Angewandte Chemie International Edition (2020).

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