Improved synthesis, characterization and catalytic application of [H(OEt2)2][B{C6H3(m-CF 3)2}4]

Hijazi AK, Taha ZA, Ajlouni A, Radhakrishnan N, Voit B, Kuehn FE (2014)

Publication Type: Journal article

Publication year: 2014

Journal

Journal of Organometallic Chemistry Elsevier

Book Volume: 763-764

Pages Range: 65-68

DOI: 10.1016/j.jorganchem.2014.04.023

Abstract

[H(OEt2)2][B{C6H3(m-CF 3)2}4] has been straightforwardly prepared through a one pot reaction. The product has been characterized by elemental and thermogravimetric analysis, 1H, 13C NMR and IR spectroscopy. The catalytic activity of the acid in the polymerization of isobutene has been studied. Polymerizations were performed at a temperature interval from 0 to 30 °C. The catalytic results show conversions between 34 and 88% and between 84 and 92% in about 30 min for complexes [H(OEt 2)2][B{C6H3(m-CF3) 2}4] and [H(OEt2)2][B(C 6F5)4], respectively. © 2014 Elsevier B.V. All rights reserved.

Involved external institutions

Jordan University of Science and Technology (JUST) / جامعة العلوم والتكنولوجيا الأردنية‎ JO Jordan (JO) Leibniz-Institut für Polymerforschung Dresden e. V. DE Germany (DE) Technische Universität München (TUM) DE Germany (DE)

How to cite

APA:

Hijazi, A.K., Taha, Z.A., Ajlouni, A., Radhakrishnan, N., Voit, B., & Kuehn, F.E. (2014). Improved synthesis, characterization and catalytic application of [H(OEt2)2][B{C6H3(m-CF 3)2}4]. Journal of Organometallic Chemistry, 763-764, 65-68. https://dx.doi.org/10.1016/j.jorganchem.2014.04.023

MLA:

Hijazi, Ahmed K., et al. "Improved synthesis, characterization and catalytic application of [H(OEt2)2][B{C6H3(m-CF 3)2}4]." Journal of Organometallic Chemistry 763-764 (2014): 65-68.

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