Reusable Copper Catechol-based Porous Polymers for the Highly Efficient Heterogeneous Catalytic Oxidation of Secondary Alcohols
Henrion M, Mohr Y, Janssens K, Smolders S, Bugaev AL, Usoltsev OA, Quadrelli EA, Wisser FM, De Vos D, Canivet J (2022)
Publication Type: Journal article
Publication year: 2022
Journal
Book Volume: 14
Article Number: e202200649
Journal Issue: 19
Abstract
New catechol-based porous polymers were synthesized and used as platforms for the heterogenization of molecular Cu complexes. The resulting Cu@CatMP-1 materials proved to be highly stable and performing catalysts for the oxidation of secondary alcohols with turnover numbers up to 6000, about 1 to 2 orders of magnitude higher than the current relevant state of the art, using catalyst loadings as low as 25 ppm of Cu. The solid catalyst proved to be recyclable for over 10 runs without detectable metal leaching and has been scaled to the gram scale. The coordination of Cu to catechol within the polymer has been evidenced by X-ray absorption spectroscopy.
Authors with CRIS profile
Involved external institutions
Katholieke Universiteit Leuven (KUL) / Catholic University of Leuven
Belgium (BE)
Southern Federal University
Russian Federation (RU)
Universität Regensburg
Germany (DE)
Université Claude Bernard Lyon 1 (UCB)
France (FR)
Belgium (BE)
Southern Federal University
Russian Federation (RU)
Universität Regensburg
Germany (DE)
Université Claude Bernard Lyon 1 (UCB)
France (FR)
How to cite
APA:
Henrion, M., Mohr, Y., Janssens, K., Smolders, S., Bugaev, A.L., Usoltsev, O.A.,... Canivet, J. (2022). Reusable Copper Catechol-based Porous Polymers for the Highly Efficient Heterogeneous Catalytic Oxidation of Secondary Alcohols. ChemCatChem, 14(19). https://doi.org/10.1002/cctc.202200649
MLA:
Henrion, Mickaël, et al. "Reusable Copper Catechol-based Porous Polymers for the Highly Efficient Heterogeneous Catalytic Oxidation of Secondary Alcohols." ChemCatChem 14.19 (2022).
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