Synthesis, crystal structure, and transistor performance of tetracene derivatives
Moon H, Zeis R, Borkent EJ, Besnard C, Lovinger AJ, Siegrist T, Kloc C, Bao Z (2004)
Publication Language: English
Publication Type: Journal article
Publication year: 2004
Journal
Book Volume: 126
Pages Range: 15322-15323
Journal Issue: 47
DOI: 10.1021/ja045208p
Abstract
The substitution of chloro or bromo groups in tetracene gives rise to the change of crystal structure, having a substantial effect on carrier transport. Halogenated tetracene derivatives were synthesized and grown into single crystals. Monosubstituted 5-bromo- and 5-chlorotetracenes have the herringbone-type structure, while 5,11-dichlorotetracene has the slipped π stacking structure. Mobility of 5,11-dichlorotetracene was measured to be as high as 1.6 cm2/V·s in single-crystal transistors. The π stacking structure, which enhances π orbital overlap and facilitates carrier transport, may thus be responsible for this high mobility.
Authors with CRIS profile
Involved external institutions
Lucent Technologies
United States (USA) (US)
Stanford University
United States (USA) (US)
Lund University / Lunds universitet
Sweden (SE)
United States (USA) (US)
Stanford University
United States (USA) (US)
Lund University / Lunds universitet
Sweden (SE)
How to cite
APA:
Moon, H., Zeis, R., Borkent, E.-J., Besnard, C., Lovinger, A.J., Siegrist, T.,... Bao, Z. (2004). Synthesis, crystal structure, and transistor performance of tetracene derivatives. Journal of the American Chemical Society, 126(47), 15322-15323. https://doi.org/10.1021/ja045208p
MLA:
Moon, Hyunsik, et al. "Synthesis, crystal structure, and transistor performance of tetracene derivatives." Journal of the American Chemical Society 126.47 (2004): 15322-15323.
BibTeX: Download