A synthetic methodology toward π-extended porphyrin-rylenediimide conjugates

Oleszak C, Ritterhoff C, Schulze E, Hirsch A, Meyer B, Jux N (2025)

Publication Type: Journal article

Publication year: 2025

Journal

RSC Advances Royal Society of Chemistry

Book Volume: 15

Pages Range: 1212-1219

Journal Issue: 2

DOI: 10.1039/d4ra08045a

Abstract

In this work, we present a straightforward synthetic route for the preparation of functionalized β-meso-fused porphyrins, which are subsequently connected to rylendiimides. The resulting donor-acceptor-type conjugates exhibit intriguing optical properties, such as panchromatism and profoundly bathochromically shifted absorption curves. A better understanding of the molecules' electronic structure was gained through density-functional theory calculations, which unveiled small HOMO-LUMO gaps.

Authors with CRIS profile

Christoph Oleszak Sonderforschungsbereich 953/3 Synthetische Kohlenstoffallotrope Christian Ritterhoff Interdisziplinäres Zentrum für Molekulare Materialien (ICMM) Erik Schulze Lehrstuhl für Organische Chemie II Andreas Hirsch Lehrstuhl für Organische Chemie II Bernd Meyer Professur für Computational Chemistry Norbert Jux Interdisziplinäres Zentrum für Molekulare Materialien (ICMM)

How to cite

APA:

Oleszak, C., Ritterhoff, C., Schulze, E., Hirsch, A., Meyer, B., & Jux, N. (2025). A synthetic methodology toward π-extended porphyrin-rylenediimide conjugates. RSC Advances, 15(2), 1212-1219. https://doi.org/10.1039/d4ra08045a

MLA:

Oleszak, Christoph, et al. "A synthetic methodology toward π-extended porphyrin-rylenediimide conjugates." RSC Advances 15.2 (2025): 1212-1219.

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