Oxygen sublattice disorder and valence state modulation in infinite-layer nickelate superlattices

Ortiz RA, Enderlein N, Fürsich K, Pons R, Radhakrishnan P, Schierle E, Wochner P, Logvenov G, Cristiani G, Hansmann P, Keimer B, Benckiser E (2025)

Publication Type: Journal article

Publication year: 2025

Journal

Physical Review Materials American Physical Society

Book Volume: 9

Article Number: 054801

Journal Issue: 5

DOI: 10.1103/PhysRevMaterials.9.054801

Abstract

The family of infinite-layer nickelates promises important insights into the mechanism of unconventional superconductivity. Since superconductivity has so far only been observed in epitaxial thin films, heteroepitaxy with the substrate or a capping layer possibly plays an important role. Here, we use soft x-ray spectroscopy to investigate superlattices as a potential approach for a targeted material design of high-temperature superconductors. We observe modulations in valence state and oxygen coordination in topotactically reduced artificial superlattices with repeating interfaces between nickelate layers and layers of materials commonly used as substrates and capping layers. Our results show that depending on the interlayer material metallic conductivity akin to the parent infinite-layer compounds is achieved. Depth-resolved electronic structure measured by resonant x-ray reflectivity reveals a reconstructed ligand field and valence state at the interface, which is confined to one or two unit cells. The central layers are predominantly monovalent nickel, but linear dichroism analysis reveals considerable disorder in the oxygen removal sites. We observe a quantitative correlation of this disorder with the interlayer material that is important for future modeling and design strategies.

Authors with CRIS profile

Niklas Enderlein Professur für Theoretische Physik mit dem Schwerpunkt Molekulare Materialien Philipp Hansmann Professur für Theoretische Physik mit dem Schwerpunkt Molekulare Materialien

Involved external institutions

Max-Planck-Institut für Festkörperforschung DE Germany (DE) Helmholtz-Zentrum Berlin für Materialien und Energie (HZB) DE Germany (DE)

How to cite

APA:

Ortiz, R.A., Enderlein, N., Fürsich, K., Pons, R., Radhakrishnan, P., Schierle, E.,... Benckiser, E. (2025). Oxygen sublattice disorder and valence state modulation in infinite-layer nickelate superlattices. Physical Review Materials, 9(5). https://doi.org/10.1103/PhysRevMaterials.9.054801

MLA:

Ortiz, R. A., et al. "Oxygen sublattice disorder and valence state modulation in infinite-layer nickelate superlattices." Physical Review Materials 9.5 (2025).

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