Carbamate-linked (oligo)phenothiazines in mesoporous silica by post-synthetic grafting: Fluorescent redox-active hybrid materials

Franz AW, Zhou Z, Turdean R, Wagener A, Sarkar B, Hartmann M, Ernst S, Thiel WR, Müller TJ (2009)

Publication Type: Journal article

Publication year: 2009

Journal

European Journal of Organic Chemistry Wiley

Pages Range: 3895-3905

Journal Issue: 23

DOI: 10.1002/ejoc.200900332

Abstract

Mesoporous hybrid, materials of (oligo)phenothiazmes cova-lently grafted onto MCM-41 or SBA-15 silica have been readily prepared from (oligo)phenothiazinyl carbamates. The phenothiazine precursors show interesting electronic proper-ties according to electronic spectroscopy and cyclic voltammetry. The resulting electronically active hybrid materials display fluorescence and can be oxidized to give stable radi-cal-cationic species upon mild oxidation. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

Authors with CRIS profile

Martin Hartmann Lehrstuhl für Katalyse und nachhaltige Verfahren

Involved external institutions

Heinrich-Heine-Universität Düsseldorf DE Germany (DE) Rheinland-Pfälzische Technische Universität Kaiserslautern-Landau (RPTU) DE Germany (DE) Universität Stuttgart DE Germany (DE)

How to cite

APA:

Franz, A.W., Zhou, Z., Turdean, R., Wagener, A., Sarkar, B., Hartmann, M.,... Müller, T.J. (2009). Carbamate-linked (oligo)phenothiazines in mesoporous silica by post-synthetic grafting: Fluorescent redox-active hybrid materials. European Journal of Organic Chemistry, 23, 3895-3905. https://doi.org/10.1002/ejoc.200900332

MLA:

Franz, Adam W., et al. "Carbamate-linked (oligo)phenothiazines in mesoporous silica by post-synthetic grafting: Fluorescent redox-active hybrid materials." European Journal of Organic Chemistry 23 (2009): 3895-3905.

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